This represents a complete OPCODE list with 14 Constants (int values) available and 10 Labels (byte values) available for creating subroutines. Constants were favored over Labels, but this is up for evaluation. NOP and HCF were both added to the official OPS-List. There is space for 2 more OPS...

0: SWP()
1: SAV()
2: NEG()
3: HCF()
4: NOP()
5: MOV(ACC,LEFT)
6: MOV(ACC,RIGHT)
7: MOV(ACC,UP)
8: MOV(ACC,DOWN)
9: MOV(ACC,ANY)
10: MOV(ACC,LAST)
11: MOV(LEFT,ACC)
12: MOV(LEFT,LEFT)
13: MOV(LEFT,RIGHT)
14: MOV(LEFT,UP)
15: MOV(LEFT,DOWN)
16: MOV(LEFT,ANY)
17: MOV(LEFT,LAST)
18: MOV(RIGHT,ACC)
19: MOV(RIGHT,LEFT)
20: MOV(RIGHT,RIGHT)
21: MOV(RIGHT,UP)
22: MOV(RIGHT,DOWN)
23: MOV(RIGHT,ANY)
24: MOV(RIGHT,LAST)
25: MOV(UP,ACC)
26: MOV(UP,LEFT)
27: MOV(UP,RIGHT)
28: MOV(UP,UP)
29: MOV(UP,DOWN)
30: MOV(UP,ANY)
31: MOV(UP,LAST)
32: MOV(DOWN,ACC)
33: MOV(DOWN,LEFT)
34: MOV(DOWN,RIGHT)
35: MOV(DOWN,UP)
36: MOV(DOWN,DOWN)
37: MOV(DOWN,ANY)
38: MOV(DOWN,LAST)
39: MOV(ANY,ACC)
40: MOV(ANY,LEFT)
41: MOV(ANY,RIGHT)
42: MOV(ANY,UP)
43: MOV(ANY,DOWN)
44: MOV(ANY,ANY)
45: MOV(ANY,LAST)
46: MOV(LAST,ACC)
47: MOV(LAST,LEFT)
48: MOV(LAST,RIGHT)
49: MOV(LAST,UP)
50: MOV(LAST,DOWN)
51: MOV(LAST,ANY)
52: MOV(LAST,LAST)
53: MOV(CONST1,ACC)
54: MOV(CONST1,LEFT)
55: MOV(CONST1,RIGHT)
56: MOV(CONST1,UP)
57: MOV(CONST1,DOWN)
58: MOV(CONST1,ANY)
59: MOV(CONST1,LAST)
60: MOV(CONST2,ACC)
61: MOV(CONST2,LEFT)
62: MOV(CONST2,RIGHT)
63: MOV(CONST2,UP)
64: MOV(CONST2,DOWN)
65: MOV(CONST2,ANY)
66: MOV(CONST2,LAST)
67: MOV(CONST4,ACC)
68: MOV(CONST4,LEFT)
69: MOV(CONST4,RIGHT)
70: MOV(CONST4,UP)
71: MOV(CONST4,DOWN)
72: MOV(CONST4,ANY)
73: MOV(CONST4,LAST)
74: MOV(CONST5,ACC)
75: MOV(CONST5,LEFT)
76: MOV(CONST5,RIGHT)
77: MOV(CONST5,UP)
78: MOV(CONST5,DOWN)
79: MOV(CONST5,ANY)
80: MOV(CONST5,LAST)
81: MOV(CONST6,ACC)
82: MOV(CONST6,LEFT)
83: MOV(CONST6,RIGHT)
84: MOV(CONST6,UP)
85: MOV(CONST6,DOWN)
86: MOV(CONST6,ANY)
87: MOV(CONST6,LAST)
88: MOV(CONST7,ACC)
89: MOV(CONST7,LEFT)
90: MOV(CONST7,RIGHT)
91: MOV(CONST7,UP)
92: MOV(CONST7,DOWN)
93: MOV(CONST7,ANY)
94: MOV(CONST7,LAST)
95: MOV(CONST8,ACC)
96: MOV(CONST8,LEFT)
97: MOV(CONST8,RIGHT)
98: MOV(CONST8,UP)
99: MOV(CONST8,DOWN)
100: MOV(CONST8,ANY)
101: MOV(CONST8,LAST)
102: MOV(CONST9,ACC)
103: MOV(CONST9,LEFT)
104: MOV(CONST9,RIGHT)
105: MOV(CONST9,UP)
106: MOV(CONST9,DOWN)
107: MOV(CONST9,ANY)
108: MOV(CONST9,LAST)
109: MOV(CONST10,ACC)
110: MOV(CONST10,LEFT)
111: MOV(CONST10,RIGHT)
112: MOV(CONST10,UP)
113: MOV(CONST10,DOWN)
114: MOV(CONST10,ANY)
115: MOV(CONST10,LAST)
116: MOV(CONST11,ACC)
117: MOV(CONST11,LEFT)
118: MOV(CONST11,RIGHT)
119: MOV(CONST11,UP)
120: MOV(CONST11,DOWN)
121: MOV(CONST11,ANY)
122: MOV(CONST11,LAST)
123: MOV(CONST12,ACC)
124: MOV(CONST12,LEFT)
125: MOV(CONST12,RIGHT)
126: MOV(CONST12,UP)
127: MOV(CONST12,DOWN)
128: MOV(CONST12,ANY)
129: MOV(CONST12,LAST)
130: MOV(CONST13,ACC)
131: MOV(CONST13,LEFT)
132: MOV(CONST13,RIGHT)
133: MOV(CONST13,UP)
134: MOV(CONST13,DOWN)
135: MOV(CONST13,ANY)
136: MOV(CONST13,LAST)
137: MOV(CONST14,ACC)
138: MOV(CONST14,LEFT)
139: MOV(CONST14,RIGHT)
140: MOV(CONST14,UP)
141: MOV(CONST14,DOWN)
142: MOV(CONST14,ANY)
143: MOV(CONST14,LAST)
144: ADD(ACC)
145: ADD(LEFT)
146: ADD(RIGHT)
147: ADD(UP)
148: ADD(DOWN)
149: ADD(ANY)
150: ADD(LAST)
151: ADD(CONST1)
152: ADD(CONST2)
153: ADD(CONST4)
154: ADD(CONST5)
155: ADD(CONST6)
156: ADD(CONST7)
157: ADD(CONST8)
158: ADD(CONST9)
159: ADD(CONST10)
160: ADD(CONST11)
161: ADD(CONST12)
162: ADD(CONST13)
163: ADD(CONST14)
164: SUB(ACC)
165: SUB(LEFT)
166: SUB(RIGHT)
167: SUB(UP)
168: SUB(DOWN)
169: SUB(ANY)
170: SUB(LAST)
171: SUB(CONST1)
172: SUB(CONST2)
173: SUB(CONST4)
174: SUB(CONST5)
175: SUB(CONST6)
176: SUB(CONST7)
177: SUB(CONST8)
178: SUB(CONST9)
179: SUB(CONST10)
180: SUB(CONST11)
181: SUB(CONST12)
182: SUB(CONST13)
183: SUB(CONST14)
184: JRO(ACC)
185: JRO(LEFT)
186: JRO(RIGHT)
187: JRO(UP)
188: JRO(DOWN)
189: JRO(ANY)
190: JRO(LAST)
191: JRO(CONST1)
192: JRO(CONST2)
193: JRO(CONST4)
194: JRO(CONST5)
195: JRO(CONST6)
196: JRO(CONST7)
197: JRO(CONST8)
198: JRO(CONST9)
199: JRO(CONST10)
200: JRO(CONST11)
201: JRO(CONST12)
202: JRO(CONST13)
203: JRO(CONST14)
204: JMP(LBL1)
205: JMP(LBL2)
206: JMP(LBL3)
207: JMP(LBL4)
208: JMP(LBL5)
209: JMP(LBL6)
210: JMP(LBL7)
211: JMP(LBL8)
212: JMP(LBL9)
213: JMP(LBL10)
214: JEZ(LBL1)
215: JEZ(LBL2)
216: JEZ(LBL3)
217: JEZ(LBL4)
218: JEZ(LBL5)
219: JEZ(LBL6)
220: JEZ(LBL7)
221: JEZ(LBL8)
222: JEZ(LBL9)
223: JEZ(LBL10)
224: JNZ(LBL1)
225: JNZ(LBL2)
226: JNZ(LBL3)
227: JNZ(LBL4)
228: JNZ(LBL5)
229: JNZ(LBL6)
230: JNZ(LBL7)
231: JNZ(LBL8)
232: JNZ(LBL9)
233: JNZ(LBL10)
234: JGZ(LBL1)
235: JGZ(LBL2)
236: JGZ(LBL3)
237: JGZ(LBL4)
238: JGZ(LBL5)
239: JGZ(LBL6)
240: JGZ(LBL7)
241: JGZ(LBL8)
242: JGZ(LBL9)
243: JGZ(LBL10)
244: JLZ(LBL1)
245: JLZ(LBL2)
246: JLZ(LBL3)
247: JLZ(LBL4)
248: JLZ(LBL5)
249: JLZ(LBL6)
250: JLZ(LBL7)
251: JLZ(LBL8)
252: JLZ(LBL9)
253: JLZ(LBL10)

254:GOTOSTART()

NOTE: Thanks to Ghazz in the TIS-100 Reddit this list has been amended to include ops like MOV(RIGHT,RIGHT) which allows the node at the right to store a variable without touching ACC.