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Hack Chat Transcript, Part 4
12/14/2022 at 21:57 • 0 comments.OK. I'll send it after this
what i'll give myself 15 more min before going back into my dank lab
the laboratory is a temple, because the chemist is a god.
well it has its perks
And here I am just writing up the "time's up" thing...
magnetron sputtering!
not all dank
yes, that would be correct
should get into that. sadly, the only thing in my shop that does not suck is the vacuum pump.
@Dan Maloney is it ok if we go a little over if I promise to clean up?
well@Thomas Shaddack well, I know a guy...
Absolutely fine! But I'll just say the official "Thanks!" and let the conversation wind down naturally.
okey
Need to work on Mg Al batteries for lower cost and material availability.
Thanks to Dave for stopping by today and to everyone for a great discussion!
it has been a pleasure. thanks for inviting me
As a comms-guy I feel like I should ask about any open-source BMS projects.
Thanks everyone!
Ahh..next time. Thank you.
You bet, I really enjoyed this one -- anytime I get to talk about plutonium is a happy time! Thanks for helping us wrap up the 2022 Hack Chat season with a bang!
Had a thought about the bidirectional buckboost. Change the architecture of e-vehicles. Have a small Li-titanate battery built in, as a low-temp tolerant high-current high-cycle tolerant primary source for the engines. Have a power bus from it to the bays with the buckboost nodes. Put anything into the bay - a conventional Li-ion battery, a hydrogen fuel cell, a turbine fed with dry-distilled waste plastic scavenged after the zombie apocalypse, a completely new emerging battery chemistry, or nothing if we conserve weight and do not need distance, and go.
@Tom Johnson not my ball of wax but I'll keep my ear out for the BMS stuff. Grateful folks are working on other pieces of the puzzle. I only have two hands
FYI, I'll be posting a transcript once things wrap up a bit, in case anyone needs a link or whatever
Mixing and matching power sources depending on the application is always a good thing to do. There are no one size fits all solutions
I guess we just need to keep charging on!
Same for stationary power. Have matching circuitry that can feed a battery bank, a hydrogen electrolyzer, whatever we got. Without having to plan for things in detail during initial build.
I haven't tried, but I would suspect some resistive heating of cold Li ion batteries might help them warm up faster. I'd be surprised if this wasn't used to some extent already, to the limits of what you could get away with without damaging things
meaning, the battery is more resistive when it's cold, so its internal resistance should warm it up a bit...
Have a big power plant made from smaller modules. If needed, break off modules and move them where they are needed more. If something fails, we degrade performance by the percentage of disabled units and continue on.
I saw somewhere a battery with built-in resistive heaters.
a nuclear reactor on every rooftop! What could possibly go wrong?
In every basement. Rooftops are for the backup generators in tsunami/flood areas.
One time we started our fuel cells up from -30C. it took a while but it worked
well, the sun itself is a nuclear reactor fed with a fossil fuel.
can't do that with nafion. ice crystals puncture the membrane
in long term, certainly not a renewable.
@Thomas Shaddack Interesting on the BB concept. As these things become more modularized and interchangable the application-space widens.
could we inhibit the formation of the crystals in some way? or make them form in a way that do not penetrate the membrane?
I say we kick the sun running out of fuel down to future generations
Carbon is a stellar nuclear waste product.
Intermediate. Iron is the final waste.
make it into diamond
Dyson Spheres!
@Tom Johnson my old company Ultracell really got into mixing and matching all kinds of modular portable power sources depending on need/availability
So white dwarfs are composed of diamond.
sure, diamond at 170 g/cc, sure
Could be handy for kinetic penetrators. Depleted uranium, eat your heart out!
'Diamond rain' falls on Saturn and Jupiter - BBC News
more accurate would be "falls *in* Saturn and Jupiter".
Old car batteries will be a plentiful resource, reusable for house power. An arrray of such units can give a megawatt or more in short term. Could be handy for DIY pulsed power fun and games.
OK kids I'm going to head into the lab to commit electrochemistry. Thanks for the conversation
Was GREAT to see you!
Ok I need to replace another aluminum take out pie plate electrode in my laptop battery cause the old one is dissolving away.
random thought. opensource potentiostats, and other electrochemistry gear.
for voltammetry and so.
yes I have baby designs. one quad op amp. Great for teaching
I'm off to cook a lasagna in an iron pan and store it with aluminum foil. Bye for now.
the i2c current-voltage sensors are great for such toying.
ina219, ina3221 and so on.
@Tom Johnson "I have backup applications for equipment sitting in unheated buildings." look at LTO batteries maybe?
Will look. Thanks.
@Tom Johnson sent you an email
@Tom Johnson "As a comms-guy I feel like I should ask about any open-source BMS projects." Yeah someone needs to release open Spec with example embedded library ready to run. it's someone on my to do list.
Something
@ILove Scotch also thanks for the conversation
Np which I could have asked more question, I dipped out eariler as had to pick up my kid. -
Hack Chat Transcript, Part 3
12/14/2022 at 21:56 • 0 commentsC14 would be a great power source with its huge lifetime and low energy betas.
yeah well be glad for Bosch-Haber Thomas!
@Dave Sopchak in the hackaday article it says "lithium-air battery" your working on. I didn't know you can reverse the process in the cell.. my only experience is with the open air ones.
Fritz Haber FTW, the man who feeds billions!
when he wasn't killing thousands!
Haber is very energy inefficient.
I saw some variants where microwaves were used instead of high pressure high temperature.
maybe they should use a C14 betavoltaic to drive Bosch Haber
I'm working on an article about improved catalysts to increase the efficiency of Haber-Bosch, FYI
That's one h--- of many C14 megacuries.
@ILove Scotch yeah in a nonaqueous Li air battery, you make lithium peroxide on discharge. That's the easy part. Oxidizing the lithium peroxide back to oxygen without trashing the battery has eluded everybody...except me ;)
Better idea. Thorium reactor and microwave synth rig. Nitrogen from air, hydrogen from water, ambient pressure microwave-assisted reaction, scalable factory that can act as local power plant when the wind gets counterrevolutional ideas and stops blowing and birdwhackers stop providing.
that nitrogen nitrogen triple bond is *not* easy to break, so it goes
microwave chemistry whacks the bonds directly without having to vibrate the whole atom including the nucleus that's there in only for a ride while taking the most mass.
Born-Oppenheimer approximation?
Catalytic nitrogen fixing bacteria with enhanced efficiency genetic would make Haber obsolete.
similar for photochemistry.
Brute force Haber is inelegant!
you know, if Bosch Haber didn't work, I'd say scrap it
Inelegant but nice to have. High volume density, and controllable.
let's talk electrolytic steel refining
It works just about as well as diesel engines work but for how long can be use it?
is it similar to copper refining, or to aluminium production? aqueous low-temp or hightemp molten salt?
@Thomas Shaddack cool with the kapton pyrolysis
alsohigh temp, the trick is to use electrochem rather than coke to be the reductant.
Not sure if this is off-topic or not. Regarding storage ... on the control side, are things moving towards standardization? Meaning inverters becoming tightly integrated with BMS systems?
but
said kapton pyrolysis could be also useful for eg. making flexible capacitive touch sensors. alternative to conductive inks.
even with aluminum, the carbon anodes get chewed up to CO2...
@Tom Johnson not off topic but I have no idea. Anyone else?
ah, so no electrorefining, more like electrowinning. i understand refining as purifying a substance that's already produced in previous step.
@tom "Meaning inverters becoming tightly integrated with BMS systems?" Nope.
@Thomas Shaddack Ah! I need to up my terminology game there ;)
I say we turn this whole inverter issue on its head (ducks)
close enough to be understood with just a single question. :D
There are the Mesa standards modbus ... which seem to be supplanted by SunSpec. I was curious as to how fast integration was being taken up.
Space vacuum mass spectroscopic refining is the way to go with unlimited solar energy.
SO MUCH ELECTROWINNING. YOU'RE GOING TO BE SICK OF ELECTROWINNING
@Dave Sopchak What do you mean about turning the inverter issue on its head?
@kjansky1 what are you working on?
as long as modbus isn't like flobus. Man I hated having to deal with the latter
A more sustainable power generation system.
sweet!
care to tell us more?
thought for inverters. I saw somewhere a 4-switch topology of a power converter. a coil. a mosfet from each its end to the ground. a mosfet from each coil end to left and right side. by pulsing the mosfets in proper order we have a buck or boost converter, and it works from left to right and from right to left as needed. a generic "glue" between batteries and power buses. (and if left and right side is connected together, and the coil gets a secondary, it's a h-bridge driver.)
also fun fact they use lithium peroxide in the space station. Eats CO2 and when it does it spits out oxygen, win win. Even better than lithium hydroxide
@Tom Johnson yet another attempt of mine at a bad joke
http://mesastandards.org/wp-content/uploads/MESA-ESS-Specification-December-2018-Version-1.pdf
Here is a link to the MESA-ESS standard if anyone is interested.@Thomas Shaddack thats just an Bi-directional buck boost convter.
I am impressed with buck/boost/inverters, it's comical how efficient, cheap and ubiquitous they've become. Bring on the GaN!
yup, another name for it (wasn't familiar with that one.)
Tom- thanks. I will look at that later
GaN for high freq compact, SiC for high voltage high power.
if anything, this chat has me opening up a dozen windows to read later ;)
Oh yes Ga devices because the element is so abundant.
SiC diodes are interesting. Schottky with very high voltage. No recovery time other than junction capacitance.
I've even heard of people using boron doped diamond for fast switching FETs
GaN! bah, SiC is where it's at :P
Since I see GaN advertised in all sorts of USB chargers, I assume costs should be dropping at some point.
hey SiC so many uses. I even use it to grind my telescope mirrors
higher index of refraction than diamond!
Don't fight. GaN and SiC both have their domains! :P Doped diamond would be LOVELY due to its extreme thermal conductivity.
You know, I think I heard that about diamond...
agreed Thomas, SiC in all HV stuffs, LV is GaN
Oh, yes, I have a 1 inch square 1mm thick piece of synthetic diamond right here...
yeah those higher bandgap/thermal conductivity stuff for the higher temps
I saw somewhere that diamond coatings could be made by electrochemistry, by high voltage electrolysis of dimethyl formamide. Or acetonitrile.
really
I will have to look that up
yep
https://www.sciencedirect.com/science/article/abs/pii/S0925963500005483
Diamond synthesis by electrolysis of acetates
A new method of electrochemical synthesis of different forms of carbon, including nanocrystalline diamond, is described. The electrolyte consists of a solution of ammonium acetate in acetic acid. The electrolysis is carried out by applying a shifted-square alternating voltage in the 10-100 Hz frequency range.
https://www.sciencedirect.com/science/article/pii/S0169433212014304
example:diamond-like carbon, hmm. I have some familiarity with that
boy who knew that diamond could be such a party killer ;)
no blood diamond!
Carbon nanotube semiconductors are the future.
so anyway when I was in grad school I worked on the electrochemistry of boron doped diamond and diamond like carbon
...thought... could blood be used as the organics-containing liquid in the coating synthesis?
...that would be seriously metal.
...and blood diamond, too.
holy cow
respect
Well, they're making synthetic diamonds out of human cremains, so that's sort of a blood diamond
only if some iron remains
although
carbon and iron have an interesting relationship
was that "cremains" intentional? That's a great word
Too much Fe in mammalian blood need to use Hemocyanin and you can generate the copper conductors at the same time.
yup. carbon dissolves in iron. hence it is not a good idea to use diamond abrasives for ferrous alloys, boron nitride is way better there.
who's the ferrous one of all?
Yes, Pretty sure it's the correct term -- at least that's what the funeral director who came to scare the hell out of us in high school religion class told us.
We should copper that.
...and molten iron is used as a solvent for carbon for one of the diamond synthesis methods.
come and get me, copper! I'm not afraid of your friends gold and silver, either!
He brought a box of them to show us -- looked like crushed gray Pringles
Wow iron + carbon and you get steel balls.
the cremains, or the diamond they made from them?
Any cold-efficient battery technologies gone mainstream? I have backup applications for equipment sitting in unheated buildings.
anything carbon-based can be used to make diamonds. the rest is just marketing.
Just the cremains lol
heard good things about lithium titanate batteries but not sure.
@Tom Johnson there's a startup in san diego that uses small fluorocarbons for solvent that work very well at low temp
I think they have a high limit to temp though
Good leads. Thanks.
if you want I can get you more detail. I was asked to review some of their stuff
https://www.researchgate.net/publication/270163726_Evaluation_of_the_low_temperature_performance_of_lithium_manganese_oxidelithium_titanate_lithium-ion_batteries_for_startstop_applications
may be relevant.@Thomas Shaddack anything carbon-based can *and should* be used to make diamonds.
fify
Fluorocarbon forever chemicals are today's PCB oils.
@Dave Sopchak sure. Email is tj800x@gmail.com.
OK. I'll send it after this
Hack Chat Transcript, Part 2 12/14/2022 at 21:56 • 0 comments
Mods please delete my last link to licap, it's is incorrect and wrong page i linked. these are standard ultracaps.
@ILove Scotch that lithium ion capacitor is not a battery, nor a hybrid. It's a capacitor. Look at that pathetic energy density. You're just shuttling ions, not doing reactions
So can you share a little more about how you got mixed up in electrochemistry? Sounds like it might be a cautionary tale...
tbh, my first exposure to it was when I was a little kid and my dad showed me the penny/salt water on a bit of paper towel/nickel battery would make a voltage
within a year I decided, hey how about a sheet of aluminum, a sheet of copper, and bleach? Got enough to run a model motor but fast!
My understanding is that all batteries -- going back 200 years depend on electrochemistry. But if the pundits are to be believed, there's a movement towards quantum (solid-state) batteries that do not make use of ionic movement or chemical reactions. Do you know anything about these next-generation of energy storage devices?
no I don't. You have linky?
Also -- if someone wanted to study battery technology -- what should they start reading to better understand the lingo & problems battery engineers try to address?
so, let's get a few things straight- a solid electrolyte does not a solid state battery make. There are volume changes on *all* battery electrodes depending on the state of charge
https://physicsworld.com/a/quantum-batteries-harvest-energy-from-light/
not heard of that before sounds interesting, just looking at -https://patentimages.storage.googleapis.com/22/0c/1d/f485c30d1ed67c/US10395850.pdf
Well -- one example:also, the definition of an anode, you know, the one Michael Faraday gave it, is an electrode that does an oxidation. An electrode that does a reduction is a cathode.
(Sorry don't have anything immediately on hand that isn't marketing spiel from some place, so I went to academia)
it doesn't matter what the voltage of the electrodes are, or if they're charging or discharging, all that matters is what they're doing- oxidation or reduction
so despite the fact that the material scientists and others don't know their terminology...
https://en.wikipedia.org/wiki/Lithium-ion_capacitor "The negative electrode or anode of the LIC is the battery type or high energy density electrode. The anode can be charged to contain large amounts of energy by reversible intercalation of lithium ions. This process is an electrochemical reaction."
Dave I meant this earlierthis more informal and ever expanding definition of "battery" and other terms kind of muddles the water. I know I can count on you all to fight the good fight!
@ILove Scotch OK, but still...they're stretching the definition there. Intercalation takes time. I'd like to see how fast they can charge or discharge it. If it's a battery, it's got a hard upper limit, otherwise you'll plate lithium out and screw up the cell
heydouble layer charging, even in solution, is much faster than a chemical reaction
it has properties of both, hence hybrid.
I would hope it cycles faster and longer than a Li battery i.e.
https://scitechdaily.com/new-high-performance-solid-state-battery-surprises-the-engineers-who-created-it/
"New High-Performance Solid-State Battery Surprises the Engineers Who Created It" with link atI mean, at the moment Li ion batteries have Li ions intercalate into graphite on the negative side, and metal oxides of phosphates on the positive side
conversion type electrodes (FeF3), sulfur or Li air? those things give you a different product upon discharge
Fe and LiF, Li2Sx, and Li2O2, respectively
What chemistries are realistic to expect in 5-10 years for C&I storage?
what does C&I mean
Commercial and Industrial.
ah
I assume that batteries will continue to be made of multiple small units, serialized and parallelized into large power/energy blocks.
it's interesting, Li ion has become so damn cheap and long life, it's a tough nut for the other stationary storage types to chase
what about molten metal batteries? that guy from MIT came up with a simple design with liquid electrodes, density-separated, and liquid molten-salt electrolyte. no membranes, no electrode lattice degradation, no expensive materials, suitable for grid storage.
credit where credit is due- Tesla has done some amazing stuff with 18650s. They still use those in the model S
@Thomas Shaddack are those a flow battery?
folks have always wanted to do sulfur batteries with molten sulfur. Sodium-sulfur with both of them molten
Sodium melts at 97C. Convenient
@Dave Sopchak Nope. It's the Ambri thing.
The ideas of all the connectors on the 18650 blocks give me the heebe-jeebies. I don't have real data for my concerns though.
"Undecided with Matt Ferrell" oh god, he gets so many things wrongs at times...
I've heard of Ambri, but don't know specifics
@ILove Scotch , all youtube videos are vetted for scientific accuracy!
please,undecided is certainly not a gospel but the best i can do as of just now in real time.
the mit guy has a whole lecture but that one is LONG.
I can look at it and get back to you
@tom should ask me, I got tons of tesla battery info lol.. sitting at my desk is Model s module, tesla Roadster module, and i'm building my own 18650/27.... lego module for future designs.
Professors, man, they just go on and on. I should know, that's what I used to do
very cool!
those 18650s are still the highest energy density cells Tesla has, iirc. The bigger ones can deliver and take more current, but at a bit of a cost in energy density
also the 18650s can be cooled better than the bigger cells
Flow batteries have that annoying membrane thingy. Though I saw a design of a chlorine flow battery, with water-tetrachlormethane (or water-hydrocarbon) systems, where there is no membrane, and the catholyte-anolyte junction is between immiscible liquids. The water phase is chloride-rich, the organic phase is solvent for chlorine. The junction happens on a layer of activated carbon with titanium-ruthenium oxide catalyst.
Is it clear that LFP (Lithium Iron Phosphate) is the safest battery for inside-the-building applications?
what's so annoying about a membrane (or a porous separator)
Agreed on FLow, PEM are expensive (to me anyways)
when I did flow batteries, we used a porous separator
Don't get me started on Nafion. I spent my whole fuel cell career showing them up ;)
@Tom Johnson yeah for existing Li ion types LiFePO4 is pretty safe, can handle higher temps...
Dead Li-ion cells, especially the pouch ones that are easy to disassemble, are a pretty good source of microporous polyolefin membranes. Pretty handy for electrochemistry.
Is there an alternative to Nafion?
sure. Sulfonated styrene-ethylene
@Dave Sopchak: you mentioned earlier that there's no solid state battery*.
=>But do you know of a technology that allows a higher density / compactness, for (extreme) miniaturization?
*refering to this:
https://www.electronics-lab.com/meet-the-tiny-100mah-rechargeable-3d-solid-state-batteries-from-iten/
Thomas- yes. Celgard separators
@Drix the reason solid electrolytes do well in teeny batteries is because the teenier the battery, the less likely the thin solid electrolyte will fail due to volume changes on change in state of charge
hiAny developments on radioisotope batteries?
that's one of the things that's hiding behind the misnomer "solid state". If they are truly solid state, why do things crack and fail, or why do dendrites get through? Solid state devices don't fail that way in normal operation
We did some experiments with laser-induced pyrolysis of kapton for graphene supercaps. With ionic liquid as electrolyte. It worked pretty well, we used the dead-battery separators with success. Also tested briefly for testtube-scale hydrogen production, also works.
@kjansky1 What, like the RTGs on the Mars rovers?
Speaking of dendrites...any way of breaking them up by vibration?
a radioisotope battery is a betavoltaic, is that what you mean?
or the RTGs?
Yes.
Solid state devices love to fail. Electromigration, in chips. Growth of intermetallic phases on bonding. Cracks and delamination on thermal cycling. And on and on and on...
yeah Tom also breaking up the solid electrolyte with vibration
yes and flash memory with ungodly high potential gradients in the gate
RTGs are just fancy thermocouple generators.
@Dave Sopchak You confused my sarcasm detector.
@kjansky1 so you mean betavoltaics
https://hackaday.com/2019/02/08/the-deep-space-energy-crisis-could-soon-be-over/
The Deep Space Energy Crisis Could Soon Be Over
On the face of it, powering most spacecraft would appear to be a straightforward engineering problem. After all, with no clouds to obscure the sun, adorning a satellite with enough solar panels to supply its electrical needs seems like a no-brainer.
@Dan Maloney Definitely not a battery. ;)
...and trapping the charge carriers in the oxide and resulting in wear in a similar mechanism as a radiation damage. (random thought, could that damage be annealed by heating the worn flash chips for prolonged period?)
I did a little work with betavoltaics when I was at LLNL
@Tom Johnson gets it ;)
Its now one of the 7 things in my head.
@kjansky1 betavoltaics (let's say one using tritium)- these things have ungodly high energy densities, but, you can only pull as much current as the betavoltaic is spitting out electrons
soso, long use, low current. You could combine one with a battery or a cap to trickle charge it for higher current demands
low current does not matter when paired with a supercap for pulsed loads, and used for a sensor that squirts data once per time.
@Thomas Shaddack great minds....
Do you have an idea how much power a plutonium RTG that used to be used in a pacemaker, might be able to produce at it's peak
wat
Problem with H3 is its relatively short half life.
they put a plutonium RTG in a pacemaker?!?!?!
yup
oy
https://www.medicaldesignandoutsourcing.com/looking-back-the-plutonium-powered-pacemaker/
MEDICAL DESIGN AND OUTSOURCING SAM BRUSCO
Looking Back: The Plutonium-Powered Pacemaker
The pacemaker has certainly had an interesting journey from its inception-it started as a hand-cranked box that, ironically, scared the life out of people because it leaned a little too close to Frankenstein-esque reanimation. Since then, the smallest model (Medtronic's Micra TPS) is about the size of a large vitamin, with a battery life of up to ten years.
Read this on Medical Design and Outsourcing
@kjansky1 what kind of time frame were you looking for? 12 year half life not good enough for you I guess
Carbon-14 could be used instead of tritium.
well Pu is a alpha emitter
oh yes we did that at LLNL too
You can use both alpha and gamma emitters with charge induction in a semiconductor junction.
and when C14 decays, you get nice N14.
H3 gets even nicer He3. N14 is rather annoyingly common.
I'm not an expert on the alpha/beta/gamma voltaics, but I'm not clueless
Hack Chat Transcript, Part 1 12/14/2022 at 21:55 • 0 comments
oh man I should put on a clean shirt
Hi Dave! We're strictly come-as-you-are around here. Thank God, because I'm rarely presentable
I'm just happy to be here, hope I can help the ball club
Excellent almost "Bull Durham" reference ;-)
we gotta build 'em one cell at a time
So last week I was down in Pasadena, visiting my friend who runs SAFCell. They make cesium dihydrogen phosphate fuel cells that run at about 250C. It's a great temperature for doing internal reforming of methanol or ammonia. It's only waste heat if you don't use it!
That's interesting, we've been talking about fuel cells lately in our editorial meetings. Like from a "whatever happened to fuel cells?" perspective.
Weren't we supposed to have fuel cells generating electricity on a building-by-building basis by now?
fuel cells are still around!
but
the ones running homes were using reformed natural gas
and we doan wanna use no fossil fuels, even efficiently
My neighborhood, I have a couple of neighbors with fuel cell cars- both the Toyota Mirai and one had a Honda Clarity
they *loved* the cars, but even here in the commie SF bay, the hydrogen filling stations have had a spotty uptime
Hi Everyone. Self introduction. I'm an embedded developer working on renewable energy communications protocols, consulting with a DC-area EPC that has intentions of getting into the storage market. Happy to help with protocol questions ... except canbus since I don't have any experience in that one.
one of my neighbors still loves his Mirai
Hi Tom!
Hi Dave. Thanks for doing this. Looking forward to making small zaps in my backyard.
Seems like that's the essential problem -- can't have a hydrogen economy until you have hydrogen demand, and the demand won't be there until there's an infrastructure to support it.
Fuel cells would still handily beat batteries for trucks- railroad too
fast refuel, and if you want MOAR ENERGY just have more hydrogen tanks. The reactant is separate from the power generation
just like with an IC engine (except so much better)
whereas with batteries, for a truck, that's a lot more weight for more range
even for a car, but 400 miles is pretty good for 99.9% of driving
Anyone working on battery trailers? That seems like a low-hanging fruit to get small EVs across the country nonstop.
you think? hauling more weight?
Wepends on weight to energy.
I've taken trips with friends here in California and from Connecticut to Ohio in the last year, and man Tesla has chargers all over the place for fast recharges
I've seen Teslas with generators stuffed in the trunk. That's kind of a solution /s
oh man
Gotta grab some lunch, brb
well, I suppose where things get sketch in the Great Basin maybe. Better to be safe
Gotta fill the interior with plants. Oh wait thats CO not CO2.
well, just have a good catalytic converter on your generator and it'll be all CO2
So Tom the closest I got to what you're doing was doing a USB device specification for portable fuel cells
boy that'd be fun with USB type C now. Charge everything direct over USB
Something else to be stolen in bad neighborhoods.
don't *even* get me started
so I was talking with Mike Malone on the splash page for this hack chat. I think rolling your own rechargeable batteries that'd work better than what you could get with Li ion right now would be...challenging
I will look for Anderson's new USB format any day.
the Aquion page that Mike linked to showed a DIY copper/zinc rechargeable battery, but it was far from optimized
I think I heard the new-er USB spec talks about pounding 200W or more?
"boy that'd be fun with USB type C now. Charge everything direct over USB"
lol I expect USB-IF will propose new plan having two 48v pair of power! i.e. now device will connect up the two different pairs in series and boom 96v aka ~500 watts of available power :P
suh-weet
get a nice little tingle if you get a frayed cord, like when i worked on my phone line with sweaty hands!
Well isn't latest usb-if spec already asking 48v?
if it is, it hasn't asked me
USB Power Delivery offers the following features:
Increased power levels from existing USB standards up to 240W.
New 28V, 36V, and 48V fixed voltages enable up to 140W, 180W and 240W power levels, respectively.
https://www.usb.org/usb-charger-pd
USB Charger (USB Power Delivery)
USB has evolved from a data interface capable of supplying limited power to a primary provider of power with a data interface. Today many devices charge or get their power from USB ports contained in laptops, workstations, docking stations, displays, cars, airplanes or even wall sockets.
yep
huh
The higher voltage makes sense. More current = fatter wires
as we now know
Wow, that is bold for a “for everyday humans” spec tho
Can't safety, OSHA i beleive. lol I should email my friend on USB-IF group.
I've read about these "everyday humans"
Haha, they’re everywhere!
But seriously, when you cross the “could potentially confuse a human heart” threshold, that’s big
That reminds me, My first prediction is USB-IF will have power pins that are longer than data pins.
in next spec.
well I guess if folks don't fry themselves often with the mains outlets, what do we have to fear from USB C connectors?
gets what happens when at 48v under load and you pull out the cable where the host/client can't detect when it's being disconnected!
gets=guess
an ordinary human becomes extraordinary?
Sparks! Fried cable ends.
OK I'm saving my questions to ask the group for the top of the hour
Is Extra Low Safety Voltage still Volts in the US and VA in Europe?
I thought VA meant watts
LOL...yea in DC it does.
funny I have an AC transformer that also lists VA
maybe I should ask for my money back
Anyone interested in miniature batteries?
Example:
https://www.electronics-lab.com/meet-the-tiny-100mah-rechargeable-3d-solid-state-batteries-from-iten/
Ooo! This is where I get to tell you all the news: there's no such thing as a solid state battery
unless, by "solid state battery", you mean "a marketing term"
Hum, How about heatstorage and using Solar cell to capture IR
that be solid state battery to me :P
well what's your definition of a battery then
does it include "pitcher and a catcher"?
I always assumed a solid state battery would be made on a semiconductor line, using something like a photolithography process. Aside from driving sensors it's not my current gig though.
input electricity, store it for x time, then able to drain electricity
well hey a capacitor does that
is a capacitor a battery?
depends on the Ultracap
capacitors aren't batteries
LTO versions
heat storage isn't batteries
energy storage? Sure
Dave are you livestreaming anywhere? Do we get to watch you type or blow stuff up in the real world?
so, to Tom's point- he mentions stuff on a semiconductor line. Transistors, ICs, diodes, resistors? That's what I call solid state. The thing is a brick that doesnt' change dimensions as it's used
Weve put in > 1MJ of maxwall ultracaps as a buffer for an EV. Now if you want to drive 1 block only could be enough to be considered an battery like storage.
Tom- that would be fun but, sadly no
Scotch, anything like the bank of caps for fixed location usage? I have motors that I'm worried about inrush against the batteries.
So, a Li ion battery, let's say graphite on the negative electrode, nickel cobalt oxide on the positive electrode, solid electrolyte in between. Did you know the negative electrode will change its volume about 12% going from fully charged to discharged?
I guess if you're calling something a battery, the expectation is that the voltage doesn't drop to half or less when it's at half capacity.
positive electrode changes volume too
good one Erik
also, speed of charge and discharge- a capacitor is *crazy fast* compared to a battery
because it's not doing chemical reactions
@TOM "I have motors that I'm worried about inrush against the batteries." Depends on how big your batteries are, if they have enough surface charge likely could handle inrush.
moving ions, at most (in the case of low voltage electrolyte batteries)
every battery is a little bit of a capacitor
but not the other way around
https://www.licaptech.com/products
Dave what aboutit's hybrid
this is a good example- why have a big honking bank of batteries when a smaller bank of batteries and some caps to handle the transients will do?
we did that with our fuel cells back in the day. HP laptops had load profiles like the flight of the bumblebee
So we're already in the middle of a lively discussion, but we'll do the official kick-off thing and say welcome to everyone to the last Hack Chat of the year! I'm Dan, I'll be moderating along with Dusan as we welcome Dave Sopchak to continue the discussion of batteries and battery engineering.
Hi Dan!
Hey Mark!
@ILove Scotch Yea, it is a general concern. I'd expect the energy-storage devices I'll be using are generalized, and so might need specific hardware in front.
Hi Everyone
Hi, I'm Dave. I first realized I had a problem with electrochemistry about 1993, and I've been in therapy ever since.
Cat therapy
Hi Dave!
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