Software: http://www.mtoussaint.de/qtdmm.html - Linux/OSX, no idea about windows software, let us know, will add to the list
Follow the instructions and solder the wires, install software and test it via serial first
http://www.davidpilling.net/wiki/index.php/VC99 - many links at the end of the page like:
http://www.amb.org/forum/diy-hacking-multimeters-for-rs232-data-logging-output-t1210.html
More: https://nathan.chantrell.net/20131015/adding-a-wireless-pc-link-to-the-vichy-vc99-multimeter/
Be aware of copy cats http://fab.cba.mit.edu/classes/863.15/doc/tutorials/programming/bluetooth/bluetooth40_en.pdf